MS Fragmentation Patterns — The High-Yield Cleavages: Mechanism + Exam Traps

Once you have the molecular ion and halogen clues, fragments tell you what substructures are present: benzylic cleavage, α-cleavage next to heteroatoms,…

  • Reaction: MS Fragmentation Patterns — The High-Yield Cleavages
  • What it does: Once you have the molecular ion and halogen clues, fragments tell you what substructures are present: benzylic cleavage, α-cleavage next to heteroatoms,…
  • Typical reagents: EI-MS fragmentation (analysis)
  • Key intermediate: Oxonium ion
  • Driving force: Formation of more stable bonds / products
  • Exam type: Interpret data
  • Exam type: Identify functional groups
  • Exam type: Structure constraints

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