EAS Halogenation: Bromination/Chlorination of Benzene (Lewis Acid Catalysis)

Learn EAS halogenation: generating Br+ (or Cl+) with FeBr3/AlCl3, sigma complex formation, and how halogens are deactivating yet ortho/para directing.

  • Reaction: Arene → haloarene
  • What it does: Installs Br or Cl onto aromatic ring
  • Typical reagents: Br2/FeBr3 or Cl2/AlCl3
  • Key intermediate: Sigma complex
  • Driving force: Re-aromatization by deprotonation
  • Exam type: Predict regio
  • Exam type: Mechanism steps

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