EAS Halogenation: Bromination/Chlorination of Benzene (Lewis Acid Catalysis)
Learn EAS halogenation: generating Br+ (or Cl+) with FeBr3/AlCl3, sigma complex formation, and how halogens are deactivating yet ortho/para directing.
- Reaction: Arene → haloarene
- What it does: Installs Br or Cl onto aromatic ring
- Typical reagents: Br2/FeBr3 or Cl2/AlCl3
- Key intermediate: Sigma complex
- Driving force: Re-aromatization by deprotonation
- Exam type: Predict regio
- Exam type: Mechanism steps