Aryl Diazonium Chemistry: Sandmeyer and Beyond: Mechanism + Exam Traps

Turn anilines into versatile aryl diazonium salts (NaNO2/HCl, 0–5 °C) and replace N2+ with Cl/Br/CN/OH and more via Sandmeyer-type reactions.

  • Reaction: Aryl Diazonium Chemistry: Sandmeyer and Beyond
  • What it does: Turn anilines into versatile aryl diazonium salts (NaNO2/HCl, 0–5 °C) and replace N2+ with Cl/Br/CN/OH and more via Sandmeyer-type reactions.
  • Typical reagents: 1) NaNO2, HCl, 0–5 °C 2) CuCl (Sandmeyer)
  • Key intermediate: Aryl diazonium
  • Driving force: Formation of more stable bonds / products
  • Exam type: Predict major product
  • Exam type: Mechanism choice

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