Cope Rearrangement: [3,3]-Sigmatropic Shift in 1,5‑Dienes

Learn the Cope rearrangement: concerted [3,3] shift of 1,5-dienes, chair transition state, and how substituents affect feasibility and product distribution.

  • Reaction: 1,5-diene → isomerized 1,5-diene
  • What it does: Rearranges sigma bond position within a diene system
  • Typical reagents: Heat
  • Key intermediate: None (concerted)
  • Driving force: Thermodynamics of substituted alkene positions
  • Exam type: Pericyclic
  • Exam type: Thermodynamics

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