Alcohol Protecting Groups: TBDMS (TBS) Ethers and Deprotection: Mechanism + Exam Traps

Protect alcohols as TBDMS (TBS) ethers (TBDMSCl + base) and remove them (TBAF or acid) to control multi-step synthesis without unwanted reactions.

  • Reaction: Alcohol Protecting Groups: TBDMS (TBS) Ethers and Deprotection
  • What it does: Protect alcohols as TBDMS (TBS) ethers (TBDMSCl + base) and remove them (TBAF or acid) to control multi-step synthesis without unwanted reactions.
  • Typical reagents: TBDMSCl, imidazole
  • Key intermediate: Varies / context-dependent
  • Driving force: Formation of more stable bonds / products
  • Exam type: Predict major product
  • Exam type: Mechanism choice

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